Water → Adipic Acid

HRID 971131Notes

Reaction equation

HRID 971131 reaction equation
F[C:2](F)(F)[C:3]([OH:5])=[O:4].[C:8]1(=[O:14])[CH2:13][CH2:12][CH2:11]CC1.[OH2:15]>>[C:3]([OH:5])(=[O:4])[CH2:2][CH2:11][CH2:12][CH2:13][C:8]([OH:14])=[O:15]

Participants

4

Reactant 3

HCID 962WaterHCID 6422Trifluoroacetic acid2×HCID 7967Cyclohexanone

Product 1

HCID 196Adipic Acid

Procedure

An operation was conducted in the same manner as in Example 1 except that trifluoroacetic acid containing 0.1 mass % of water was replaced by an aqueous solution containing 93.1 mass % (90 volume %) of trifluoroacetic acid and that cyclohexanone was used as a raw material for reaction. As a result, no adipic acid (intended product) was obtained and cyclohexanone used as a raw material was recovered quantitatively.

Sources & evidence

ORD record
ord-42c1c89a99654537aaf4b6eccbb68b1b
Source dataset
uspto-grants-2007_12
Patent number
US07312357B2

Reaction notes

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