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HRID971434

反应详情

EQUATION

反应方程式

HRID 971434 的结构方程式

REACTANTS

反应物

4
结构：COC=O
HCID7865

Methyl formate

C2H4O2

结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：CC1=C2CC[C@H]3[C@@H]4CC[C@H](O)[C@@]4(C)CC[C@@H]3[C@@]2(C)CCC1=O
HCID236536

4-Methyltestosterone

C20H30O2

结构：CC1=C2CC[C@@H]3[C@H](CC[C@@]4(C)[C@H]3CC[C@]4(C)O)[C@@]2(C)CC(=CO)C1=O
HCID57349609

17-Hydroxy-2-(hydroxymethylidene)-4,17-dimethylandrost-4-en-3-one

C22H32O3

PRODUCTS

生成物

1
结构：CC1=C2CC[C@H]3[C@@H]4CC[C@H](O)[C@@]4(C)CC[C@@H]3[C@@]2(C)CC(=CO)C1=O
HCID70603288

未命名化合物

PROCEDURE

实验过程

2-Hydroxymethylene-17β-hydroxy-4-methylandrost-4-en-3-one was prepared from 32.28 g. of 17β-hydroxy-4-methylandrost-4-en-3-one and 32 ml. of methyl formate by a procedure analogous to that of Example 1, part (c) except that sodium hydride (15 g., 50%) was used in place of sodium methoxide. The 20 g. of product obtained was used directly in the next reaction.

WORKUP

后处理

  1. customof product obtained
  2. customwas used directly in the next reaction