Hydrogen Peroxide → 1,1'-Dihydroxydicyclohexyl peroxide

HRID 971596Notes

Reaction equation

HRID 971596 reaction equation
[OH:1][OH:2].[C:3]1(=[O:9])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]1>O>[CH2:6]1[CH2:7][CH2:8][C:3]([O:1][O:2][C:3]2([OH:9])[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4]2)([OH:9])[CH2:4][CH2:5]1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 7967Cyclohexanone

Product 1

HCID 754771,1'-Dihydroxydicyclohexyl peroxide

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

In a 200 ml, 3-neck round-bottom flask equipped with a magnetic stirring bar, two addition funnels, and a thermometer, was placed 20.45 ml. of 30% hydrogen peroxide. One addition funnel was charged with 41.3 ml. of distilled cyclohexanone and the other with 82.6 ml of water. The contents of the two addition funnels were discharged gradually and constantly into the stirred round-bottom flask whose contents were kept at a constant temperature of about 25°-26° C. No exothermicity was noted. After both addition funnels were emptied into the round-bottom flask stirring was continued overnight.

Workup

  1. customIn a 200 ml, 3-neck round-bottom flask equipped with a magnetic stirring bar
  2. additiontwo addition funnels
  3. additionOne addition funnel
  4. additionwas charged with 41.3 ml
  5. additionThe contents of the two addition funnels
  6. customwere kept at a constant temperature of about 25°-26° C
  7. customAfter both addition funnels were emptied into the round-bottom flask

Sources & evidence

ORD record
ord-bf2250b93e4440b8a6bfe4f18e2af8f5
Source dataset
uspto-grants-1979_07
Patent number
US04160769

Reaction notes

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