HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Hydroxide → Bis[2-hydroxy-3-(7,7,8,9,9-pentamethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]phthalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 1,2-Bis(2-oxiranylmethyl) 1,2-benzenedicarboxylate | HCID 62629 | — |
| Reactant | 7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione | HCID 20481853 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Bis[2-hydroxy-3-(7,7,8,9,9-pentamethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]phthalate | HCID 86736589 | — |
Reaction Steps
24.0 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 12.0 g of bis(2,3-epoxypropyl)phthalate and 0.5 g of potassium hydroxide were reacted in 200 ml of N,N-dimethylformamide, following substantially the same procedure as in Example 1. The desired Compound No. 130 was obtained in the form of a white powder, having an Rf value of 0.47 on thin-layer chromatography on silica gel using a 8:1:1:1 by volume mixture of ethyl acetate, benzene, ethanol and triethylamine as developing solvent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04162246 |
| Source dataset | uspto-grants-1979_07 |
| ORD ID | ord-13fb8b2cf419456bb43cc66ff60a58d0 |
| Source note | uspto-grants-1979_07 |