HRID972017

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14797

Potassium hydroxide

HKO

HCID62629

1,2-Diglycidyl phthalate

C14H14O6

HCID20481853

7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione

C12H21N3O2

PRODUCTS

生成物

结构：CN1C(C)(C)CC2(CC1(C)C)NC(=O)N(CC(O)COC(=O)c1ccccc1C(=O)OCC(O)CN1C(=O)NC3(CC(C)(C)N(C)C(C)(C)C3)C1=O)C2=O

HCID86736589

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

24.0 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 12.0 g of bis(2,3-epoxypropyl)phthalate and 0.5 g of potassium hydroxide were reacted in 200 ml of N,N-dimethylformamide, following substantially the same procedure as in Example 1. The desired Compound No. 130 was obtained in the form of a white powder, having an Rf value of 0.47 on thin-layer chromatography on silica gel using a 8:1:1:1 by volume mixture of ethyl acetate, benzene, ethanol and triethylamine as developing solvent.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-13fb8b2cf419456bb43cc66ff60a58d0
来源数据集: uspto-grants-1979_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04162246
来源说明: uspto-grants-1979_07

反应 SMILES

[CH3:1][C:2]1([CH3:17])[N:13]([CH3:14])[C:12]([CH3:16])([CH3:15])[CH2:11][C:4]2([NH:8][C:7](=[O:9])[NH:6][C:5]2=[O:10])[CH2:3]1.[O:18]1[CH2:37][CH:19]1[CH2:20][O:21][C:22](=[O:36])[C:23]1[C:24](=[CH:32][CH:33]=[CH:34][CH:35]=1)[C:25]([O:27][CH2:28][CH:29]1[O:31][CH2:30]1)=[O:26].[OH-:38].[K+]>CN(C)C=O>[OH:18][CH:19]([CH2:37][N:6]1[C:5](=[O:38])[C:4]2([CH2:3][C:2]([CH3:1])([CH3:17])[N:13]([CH3:14])[C:12]([CH3:16])([CH3:15])[CH2:11]2)[NH:8][C:7]1=[O:9])[CH2:20][O:21][C:22](=[O:36])[C:23]1[C:24](=[CH:32][CH:33]=[CH:34][CH:35]=1)[C:25]([O:27][CH2:28][CH:29]([OH:31])[CH2:30][N:6]1[C:5](=[O:10])[C:4]2([CH2:3][C:2]([CH3:17])([CH3:1])[N:13]([CH3:14])[C:12]([CH3:16])([CH3:15])[CH2:11]2)[NH:8][C:7]1=[O:9])=[O:26]