HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Hydroxide → Ethylene glycol bis[2hydroxy-3-(7,7,8,9,9-pentamethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]ether
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | Glycol diglycidyl ether | HCID 16683 | — |
| Reactant | 7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione | HCID 20481853 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Ethylene glycol bis[2hydroxy-3-(7,7,8,9,9-pentamethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]ether | HCID 131711583 | — |
Reaction Steps
10.0 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 3.0 g of ethylene glycol bis(2,3-epoxypropyl)ether and 0.1 g of potassium hydroxide were reacted in 60 ml of methanol, following substantially the same procedure as in Example 1. The desired Compound No. 166 was obtained in the form of white crystals, melting at 213°-215° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04162246 |
| Source dataset | uspto-grants-1979_07 |
| ORD ID | ord-1a8c848fd0f7414d9307f74c4b6ab85f |
| Source note | uspto-grants-1979_07 |