HRID972019

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14797

Potassium hydroxide

HKO

HCID16683

未命名化合物

HCID20481853

7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione

C12H21N3O2

PRODUCTS

生成物

结构：CN1C(C)(C)CC2(CC1(C)C)NC(=O)N(CC(O)COCCOCC(O)CN1C(=O)NC3(CC(C)(C)N(C)C(C)(C)C3)C1=O)C2=O

HCID131711583

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

10.0 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 3.0 g of ethylene glycol bis(2,3-epoxypropyl)ether and 0.1 g of potassium hydroxide were reacted in 60 ml of methanol, following substantially the same procedure as in Example 1. The desired Compound No. 166 was obtained in the form of white crystals, melting at 213°-215° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1a8c848fd0f7414d9307f74c4b6ab85f
来源数据集: uspto-grants-1979_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04162246
来源说明: uspto-grants-1979_07

反应 SMILES

[CH3:1][C:2]1([CH3:17])[N:13]([CH3:14])[C:12]([CH3:16])([CH3:15])[CH2:11][C:4]2([NH:8][C:7](=[O:9])[NH:6][C:5]2=[O:10])[CH2:3]1.[O:18]1[CH2:29][CH:19]1[CH2:20][O:21][CH2:22][CH2:23][O:24][CH2:25][CH:26]1[O:28][CH2:27]1.[OH-:30].[K+]>CO>[OH:18][CH:19]([CH2:29][N:6]1[C:5](=[O:30])[C:4]2([CH2:3][C:2]([CH3:1])([CH3:17])[N:13]([CH3:14])[C:12]([CH3:16])([CH3:15])[CH2:11]2)[NH:8][C:7]1=[O:9])[CH2:20][O:21][CH2:22][CH2:23][O:24][CH2:25][CH:26]([OH:28])[CH2:27][N:6]1[C:5](=[O:10])[C:4]2([CH2:3][C:2]([CH3:17])([CH3:1])[N:13]([CH3:14])[C:12]([CH3:16])([CH3:15])[CH2:11]2)[NH:8][C:7]1=[O:9]