Hydrochloric Acid → molybdenum N,N-dimethylaniline

HRID 972471Notes

Reaction equation

HRID 972471 reaction equation
Cl.[CH3:2][N:3]([CH3:10])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[NH4+].[O-][Mo:13]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O>O>[Mo:13].[CH3:2][N:3]([CH3:10])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

5

Reactant 3

HCID 313Hydrochloric Acid2×HCID 949N,N-DimethylanilineHCID 21895884Azanium bis(dioxido(dioxo)molybdenum)

Product 1

HCID 131710929molybdenum N,N-dimethylaniline

Reagents, catalysts & solvents 1

HCID 962WaterSolvent3×

Procedure

N,N-dimethylaniline molybdate having a 2/1 molybdenum/N,N-dimethylaniline molar ratio was prepared in the presence of HCl as follows. 10 grams of N,N-dimethylaniline, 16.26 grams of a 37 wt.% aqueous HCl solution, and 250 ml water were dissolved together and heated to reflux in a 500 ml round-bottomed flask equipped with a water-cooled condenser. 28.05 grams of ammonium dimolybdate was dissolved in 52 ml hot water and then added to the first solution.

Workup

  1. temperatureheated
  2. temperatureto reflux in a 500 ml round-bottomed flask
  3. temperaturecooled condenser
  4. additionadded to the first solution

Sources & evidence

ORD record
ord-618e85c18d22427aa7a6d5102dac49f2
Source dataset
uspto-grants-1977_10
Patent number
US04053455

Reaction notes

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