Methyl bromoacetate → 1-Methoxycarbonylmethyl-7,8-dihydro-2,5(1H,6H)-quinolinedione

HRID 974259Notes

Reaction equation

[NH:1]1[C:10]2[CH2:9][CH2:8][CH2:7][C:6](=[O:11])[C:5]=2[CH:4]=[CH:3][C:2]1=[O:12].Br[CH2:14][C:15]([O:17][CH3:18])=[O:16]>>[CH3:18][O:17][C:15]([CH2:14][N:1]1[C:10]2[CH2:9][CH2:8][CH2:7][C:6](=[O:11])[C:5]=2[CH:4]=[CH:3][C:2]1=[O:12])=[O:16]

Participants

Reactant 2

HCID 60984Methyl bromoacetate

HCID 2674502-Hydroxy-7,8-dihydro-5(6H)-quinolinone

Product 1

HCID 199860021-Methoxycarbonylmethyl-7,8-dihydro-2,5(1H,6H)-quinolinedione

Procedure

Prepared analogously to Example 29 from 7,8-dihydro- 2,5(1H,6H)-quinolinedione and methyl bromoacetate.

Sources & evidence

ORD record: ord-57d8c30457f24cbab535f9c7125eb810
Source dataset: uspto-grants-1991_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05068334

Reaction notes

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