Ethyl Acetate → HCID 11778544, compound

HRID 974280Notes

Reaction equation

[CH:1](=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[C:16]([O:19][CH2:20][CH3:21])(=[O:18])[CH3:17]>>[C:16]([O:19][CH2:20][CH3:21])(=[O:18])/[CH:17]=[CH:14]/[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

Reactant 2

HCID 8857Ethyl Acetate

HCID 31291Tetradecanal

Product 1

HCID 11778544HCID 11778544, compound

Procedure

IR (thin film) 2920, 2850, 1725, 1465, 1265, 1175, 1045 cm-1 ; 1H NMR (CDCl3, 300 MHz) δ7.00 (dt, 1, J=15.5, 6.8 Hz, CH2CH=), 5.84 (dt, 1, J=15.5, 1.2 Hz, COCH=), 4.21 (dd, 2, J=14.2, 7.2 Hz, CH2O), 2.23 (qd, 2, J=6.9, 1.2 Hz, CH2CH=), 1.49 (t, 2, J=7 Hz, CH2CH2CH3), 1.3 (m, 20, CH2CH2CH2), 0.92 (t, 3, J=7 Hz, CH2CH2CH3). Rf (5% ethyl acetate:hexanes):tetradecanal, 0.29; ester product, 0.31. MS (FD): m/e 282 (M+).

Sources & evidence

ORD record: ord-fd12e5cc63c2456994cdfaf17b33ef16
Source dataset: uspto-grants-1991_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05068345

Reaction notes

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