Methanol → HCID 19050689, compound

HRID 974668Notes

Reaction equation

HRID 974668 reaction equation
[Mg:1].[CH3:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][C:11]1[CH:12]=[CH:13][C:14](O)=[CH:15][CH:16]=1.[CH3:18][OH:19]>>[CH2:10]([C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][C:16]=1[O-:19])[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2].[Mg+2:1].[CH2:7]([C:6]1[CH:5]=[CH:4][CH:3]=[CH:2][C:18]=1[O-:19])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:16][CH2:15][CH2:14][CH3:13]

Participants

4

Reactant 3

HCID 887MethanolHCID 17524-NonylphenolHCID 5462224Magnesium4×

Product 1

HCID 19050689HCID 19050689, compound

Procedure

Magnesium nonylphenoxide was prepared by reacting magnesium turnings (52 grams) with methanol (100 grams) in a three-liter three-neck flask fitted with stirrer, condenser, thermometer and nitrogen inlet. Magnesium turnings were added in 5-gram portions every 10 minutes and the exothermio reaction was controlled at 35° to 45° C. with the aid of an ice water bath. When all the magnesium was reacted, nonylphenol (880 grams) was added. The resulting solution contained 2.7% soluble magnesium according to atomic absorption analysis.

Workup

  1. customfitted with stirrer, condenser
  2. customthe exothermio reaction
  3. customwas controlled at 35° to 45° C. with the aid of an ice water bath

Sources & evidence

ORD record
ord-62fc5616c65c49b5b16b2428f2be1e2e
Source dataset
uspto-grants-1991_11
Patent number
US05068456

Reaction notes

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