Methanesulfonyl chloride → 2-Methanesulfonyloxypentadecane

HRID 974750Notes

Reaction equation

[CH3:1][CH:2]([OH:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[CH3:17][S:18](Cl)(=[O:20])=[O:19].C(N(C(C)C)CC)(C)C>>[CH3:17][S:18]([O:16][CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[CH3:1])(=[O:20])=[O:19]

Participants

Reactant 3

HCID 31297Methanesulfonyl chloride

HCID 81531Diisopropylethylamine

HCID 96687Pentadecan-2-ol

Product 1

HCID 153433082-MethanesulfonyloxypentadecaneYield 95%

Procedure

The 2-methanesulfonyloxypentadecane was prepared from 2-pentadecanol (25 g, 109 mmol), methanesulfonylchloride (11.8 ml, 152 mmol) and diisopropylethylamine (22.8 ml, 131 mmol) as previously described in 95% yield.

Sources & evidence

ORD record: ord-775889c9293040eca74b95c3c9cb9b10
Source dataset: uspto-grants-1997_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05607660

Reaction notes

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