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N-Allyl-N-(1,1-dimethoxyprop-2-yl)-urethane → Ethyl N-allyl-N-(1-oxoprop-2-yl)-carbamate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-Allyl-N-(1,1-dimethoxyprop-2-yl)-urethane | HCID 15069988 | — |
| 溶媒 | Formic Acid | HCID 284 | — |
| 生成物 | Ethyl N-allyl-N-(1-oxoprop-2-yl)-carbamate | HCID 15069993 | — |
反応手順
76.5 g (0.213 mol) of 64.5% pure N-allyl-N-(1,1-dimethoxyprop-2-yl)-urethane are heated in 180 ml of formic acid at 100° C. for one hour. The mixture is poured into ice-water and extracted with CH2Cl2, the extracts are washed neutral with NaHCO3 solution, dried over MgSO4 and concentrated and the residue is distilled.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05607942 |
| 出典データセット | uspto-grants-1997_03 |
| ORD ID | ord-0457777cb6f44f7787d9c40a78e8996c |
| 出典メモ | uspto-grants-1997_03 |