Diethyl Ether → 4,6,6-Trimethyl-1,3-cyclohexadiene-1-methanol

HRID 97674Notes

Reaction equation

HRID 97674 reaction equation
[Al+3:13].[CH2:18]([O:19][CH2:20][CH3:21])[CH3:22].[CH3:1][C:2]1=[CH:3][CH:4]=[C:5]([CH:10]=[O:11])[C:6]([CH3:8])([CH3:9])[CH2:7]1.[H-:12].[H-:15].[H-:16].[H-:17].[Li+:14]>>[CH3:1][C:2]1=[CH:3][CH:4]=[C:5]([CH2:10][OH:11])[C:6]([CH3:8])([CH3:9])[CH2:7]1

Participants

6

Reactant 5

HCID 3283Diethyl EtherHCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 109206834,6,6-Trimethyl-1,3-cyclohexadiene-1-carboxaldehyde

Product 1

HCID 212637434,6,6-Trimethyl-1,3-cyclohexadiene-1-methanol

Sources & evidence

ORD record
ord-cb5475fc71c9416cb14857fd37237a00
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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