HCID 86750595, compound → HCID 86750594, compound

HRID 977074Notes

Reaction equation

HRID 977074 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[CH:15](/[CH:16]=[CH:17]/[C:18]([O:20][CH3:21])=[O:19])[CH:14]3[N:9]([CH2:10][CH2:11][C:12]4[CH:25]=[CH:24][CH:23]=[CH:22][C:13]=43)[C:8](=[O:26])[C:7]=2[CH:27]=1>C1(C)C=CC=CC=1>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[C:15](/[CH:16]=[CH:17]/[C:18]([O:20][CH3:21])=[O:19])=[C:14]3[N:9]([CH2:10][CH2:11][C:12]4[CH:25]=[CH:24][CH:23]=[CH:22][C:13]=43)[C:8](=[O:26])[C:7]=2[CH:27]=1

Participants

3

Reactant 1

HCID 86750595HCID 86750595, compound

Product 1

HCID 86750594HCID 86750594, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

5.5 g (15.13 mmol) of methyl (E)-3-(10-methoxy-8-oxo-5,8,13,13a-tetrahydro-6H-dibenzo[a,g]quinolizin-13-yl)prop-2-enoate are dissolved in 150 ml of toluene in a 500 ml round-bottomed flask, 5.15 g (22.7 mmol) of 2,3-dichloro-5,6-dicyanocyclohexa-2,5-diene-1,4-diene are added and the mixture is heated at reflux for 2 h 30.

Workup

  1. temperaturethe mixture is heated
  2. temperatureat reflux for 2 h 30

Sources & evidence

ORD record
ord-d9b91f49868343afaa01ef64ed382df0
Source dataset
uspto-grants-1997_03
Patent number
US05614517

Reaction notes

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