Acetic Acid → Benzoic Acid

HRID 978796Notes

Reaction equation

HRID 978796 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)(=[O:3])C.[C:10](O)(=[O:12])C>>[C:1]([OH:3])(=[O:12])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH2:10]=[O:12]

Participants

4

Reactant 2

HCID 176Acetic AcidHCID 7410Acetophenone

Product 2

HCID 243Benzoic AcidHCID 712Formaldehyde

Procedure

Khandual et al., J. Indian Chem. Soc., 49, 557-560 (Eng.) (1972) as abstracted in C.A. (1972), 77, 125628g, show the oxidation of acetophenone in 95% acetic acid by manganic acetate to form benzoic acid, and formaldehyde. The oxidation of acetophenone containing ring substituents, e.g., methoxy, is also taught.

Sources & evidence

ORD record
ord-8d420019aaa14445bb7aa04aa6b2f197
Source dataset
uspto-grants-1987_05
Patent number
US04665215

Reaction notes

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