Methyl Acrylate → HCID 21621278, compound

HRID 979259Notes

Reaction equation

HRID 979259 reaction equation
[CH2:1]([N:8]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[OH:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:17]([O:21][CH3:22])(=[O:20])[CH:18]=[CH2:19].[CH3:23]C(C)([O-])C.[K+]>C(O)C>[CH2:22]([O:21][C:17](=[O:20])[CH2:18][CH2:19][O:9][N:8]([CH2:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[CH3:23]

Participants

5

Reactant 3

HCID 7294Methyl AcrylateHCID 69297DibenzylhydroxylamineHCID 23665647Potassium tert-butoxide

Product 1

HCID 21621278HCID 21621278, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The procedure of Example I is repeated using 21.33 g of N,N-dibenzylhydroxylamine, 10.33 g of methyl acrylate and 1.0 g of potassium-tert-butoxide in 100 ml of ethanol, to afford the title compound as a colorless liquid.

Sources & evidence

ORD record
ord-b417e237050f4db9bad98a5a7bdc0094
Source dataset
uspto-grants-1987_05
Patent number
US04666962

Reaction notes

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