Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | Allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride | HCID 54206110 | — |
| Product | HCID 178438298 | HCID 178438298 | — |
Reaction Steps
93 g of aniline are added dropwise to 102 g of allyl-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid anhydride, while stirring. During this addition, the temperature rises to 80° C. The mixture is heated to 150° C. and the pressure is reduced to 4,266 Pa. 9 ml of water and 46 ml of aniline distil off. Distillation gives 82.37 g (60% of theory) of a viscous yellow oil of boiling point 183° C. under 12 Pa, nD20 1.5738 and η25 105.6 Pa.s.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04667003 |
|---|
| Source dataset | uspto-grants-1987_05 |
|---|
| ORD ID | ord-49922f24ade541e2b8f5cd7927291618 |
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| Source note | uspto-grants-1987_05 |
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