HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetaldehyde → 4-Acetyl-3H-phenothiazin-3-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetaldehyde | HCID 177 | — |
| Reactant | Phenothiazone | HCID 68485 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 4-Acetyl-3H-phenothiazin-3-one | HCID 13853726 | — |
Reaction Steps
A solution of 3H-phenothiazin-3-one (2 g) and acetaldehyde (32 ml) in benzene (240 ml) was irradiated with a 450 watt lamp for 2 days. The volatiles were removed under vacuum and the residue chromatographed on a silica gel column eluting with 25% EtOAc/hexane to afford the desired compound, m.p. 222° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04667032 |
| Source dataset | uspto-grants-1987_05 |
| ORD ID | ord-99fa7876c4f74808a4e2a42adf1d7c59 |
| Source note | uspto-grants-1987_05 |