Potassium Bromide → HCID 13920717, compound

HRID 979551Notes

Reaction equation

[C:1]1([CH3:11])[CH:6]=[CH:5][C:4]([S:7]([OH:10])(=[O:9])=[O:8])=[CH:3][CH:2]=1.[CH2:12]([O:20][C:21](=[O:30])[CH2:22][CH2:23][CH:24]([NH2:29])[C:25](C)=[C:26]=[CH2:27])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[K+].[Br-]>>[C:1]1([CH3:11])[CH:2]=[CH:3][C:4]([S:7]([OH:10])(=[O:8])=[O:9])=[CH:5][CH:6]=1.[NH2:29][CH:24]([CH:25]=[C:26]=[CH2:27])[CH2:23][CH2:22][C:21]([O:20][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:30]

Participants

Reactant 2

HCID 253877Potassium Bromide

HCID 13920720HCID 13920720, compound

Product 1

HCID 13920717HCID 13920717, compound

Procedure

In the same manner, octyl-4-amino-5-methyl-5,6-heptadienoate para-toluene-sulfonic acid salt was made. mp. 62° C., IR (KBr): 1760, 1725 cm-1 ; 'H NMR (δCDCl3): 0.8-2.5 (m, 21H), 2.37 (s, 3H, CH3Ph), 3.7 (m, 1H, CHN), 4.0 (t, 2H, J=6.7 Hz, OCH2), 4.9 (m, 2H, H2C=C), 7.15, 7.77 (d, 4H, Ph), 7.25 (broad s, 3H, NH, OH).

Sources & evidence

ORD record: ord-2de9a426524d4349a157f9cab3aff791
Source dataset: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04668703

Reaction notes

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