6-Benzamidohexanoic acid → HCID 53799883, compound

HRID 979752Notes

Reaction equation

HRID 979752 reaction equation
B([O:3][O-:4])=O.O.[Na+].[Na].[C:8]([NH:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22](O)=[O:23])(=[O:15])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>O>[C:8]([NH:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][C:22]([O:3][OH:4])=[O:23])(=[O:15])[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

Participants

5

Reactant 3

HCID 703886-Benzamidohexanoic acidHCID 5360545SodiumHCID 23695970Perboric acid, sodium salt, monohydrate

Product 1

HCID 53799883HCID 53799883, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Perhydrolysis of the above phenolsulfonate ester to yield 6-benzoylaminoperoxycaproic acid was accomplished according to the following procedure. To 4 L of 95° F. city water was added 5.00 g (1250 ppm) of an alkaline detergent granule, 0.36 g (90 ppm) of sodium perborate monohydrate and 0.46 g (115 ppm) of the sodium salt of the phenolsulfonate ester of 6-benzoylaminocaproic acid (0.67 g of the 69% mixture described above). Perhydrolysis of the ester to form 6-benzoylamino-peroxycaproic acid was followed by analysis of the solution for available oxygen (AvO) using a conventional iodometric titration. Complete conversion of the ester to the peroxyacid would result in the formation of 4.5 ppm AvO. The results obtained for AvO versus time are tabulated below.

Sources & evidence

ORD record
ord-ed2b13da26ca4d7fa50f79178a4f3ee9
Source dataset
uspto-grants-1987_01
Patent number
US04634551

Reaction notes

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