tert-Butyl hydroperoxide → HCID 20222585, compound

HRID 979755Notes

Reaction equation

HRID 979755 reaction equation
[CH:1]([CH:4]1[C:13]2[CH2:12][C:11]([CH3:14])=[CH:10][CH2:9][C:8]=2[C:7]([CH3:16])([CH3:15])[CH2:6][CH2:5]1)([CH3:3])[CH3:2].P([O-])([O-])(O)=[O:18].[Na+].[Na+].C(OO)(C)(C)C>ClC(Cl)C.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mo]>[O:18]1[C:11]2([CH3:14])[CH:10]1[CH2:9][C:8]1[C:7]([CH3:16])([CH3:15])[CH2:6][CH2:5][CH:4]([CH:1]([CH3:3])[CH3:2])[C:13]=1[CH2:12]2

Participants

6

Reactant 3

HCID 6410tert-Butyl hydroperoxideHCID 24203Sodium Phosphate, DibasicHCID 20222580HCID 20222580, compound

Product 1

HCID 20222585HCID 20222585, compound

Reagents, catalysts & solvents 2

HCID 98885Molybdenum carbonyl (Mo(CO)6)CatalystHCID 63651,1-DichloroethaneSolvent

Procedure

105 g of a hydrocarbon mixture containing (according to GC) 56% of 1-isopropyl-4,4,7-trimethyl-1,2,3,4,5,8-hexahydronaphthalene (IIo) are dissolved in 400 ml of dichloroethane and treated in accordance with Example 1, method C, with 1.1 g of molybdenum hexacarbonyl, 0.4 g of disodium hydrogen phosphate and 228 ml of a 2.8 molar tert.butyl hydroperoxide solution. After working-up, 115 g of crude product are obtained. By chromatography there is obtained pure 6,7-epoxy-1-isopropyl-4,4,7-trimethyl1,2,3,4,5,6,7,8-octahydronaphthalene.

Workup

  1. custom115 g of crude product are obtained

Sources & evidence

ORD record
ord-33aee116bfdc4172ad9ccdbe44c09a62
Source dataset
uspto-grants-1987_01
Patent number
US04634548

Reaction notes

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