Hydrogen Peroxide → HCID 12610196, compound

HRID 979979Notes

Reaction equation

HRID 979979 reaction equation
[N:1]1[C:14]2[NH:13][C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[S:6][C:5]=2[N:4]=[CH:3][CH:2]=1.[OH:15]O>C(O)(=O)C>[N:1]1[C:14]2[NH:13][C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[S:6](=[O:15])[C:5]=2[N:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 12351784HCID 12351784, compound

Product 1

HCID 12610196HCID 12610196, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

To 1,4-diaza-10H-phenothiazine (1 g, 5 mmoles) in acetic acid (15 ml) was added 50% hydrogen peroxide (1 ml). The mixture was stirred at 55° for 30 minutes. The mixture was evaporated to a small volume and the title compound crystallized out. The crystals were filtered, washed with acetic acid and air dried to yield 983 mg of the title compound, m.p. 261°-263°.

Workup

  1. customThe mixture was evaporated to a small volume
  2. customthe title compound crystallized out
  3. filtrationThe crystals were filtered
  4. washwashed with acetic acid and air
  5. customdried

Sources & evidence

ORD record
ord-ccffd4cb476f4b6db33110fd996020c2
Source dataset
uspto-grants-1987_01
Patent number
US04634766

Reaction notes

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