Isopropanol → HCID 86741194, compound

HRID 980028Notes

Reaction equation

HRID 980028 reaction equation
CC(C[Al](CC(C)C)CC(C)C)C.[CH3:14][CH:15]([CH2:18][CH2:19][CH3:20])[CH2:16][OH:17].[CH:21]([OH:24])([CH3:23])[CH3:22]>CCCCCCC.C1CCCCC1>[CH3:14][CH:15]([CH2:18][CH2:19][CH3:20])[CH2:16][OH:17].[CH:21]([OH:24])([CH3:23])[CH3:22]

Participants

6

Reactant 3

HCID 3776IsopropanolHCID 77452-Methyl-1-pentanolHCID 16682931Triisobutylaluminum

Product 1

HCID 86741194HCID 86741194, compound

Reagents, catalysts & solvents 2

HCID 8078CyclohexaneSolventHCID 8900HeptaneSolvent

Procedure

To 10 ml of 1.085M DBM in heptane and 0.33 ml of 0.92M TIBAL (as above) is slowly added a mixture of 2-methyl-1-pentanol (1.34 ml, 10.85 mmoles) and isopropanol (0.82 ml, 10.85 mmoles) diluted to 5 ml with cyclohexane. Again, a clear, stable solution results at room temperature.

Workup

  1. customAgain, a clear, stable solution results at room temperature

Sources & evidence

ORD record
ord-c880ef94e4e743bcb163c4605b874c06
Source dataset
uspto-grants-1987_01
Patent number
US04634786

Reaction notes

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