Isopropanol → HCID 86741194, compound

HRID 980029Notes

Reaction equation

HRID 980029 reaction equation
CC(C[Al](CC(C)C)CC(C)C)C.[CH3:14][CH:15]([CH2:18][CH2:19][CH3:20])[CH2:16][OH:17].[CH:21]([OH:24])([CH3:23])[CH3:22]>CCCCCCC.C1CCCCC1>[CH3:14][CH:15]([CH2:18][CH2:19][CH3:20])[CH2:16][OH:17].[CH:21]([OH:24])([CH3:23])[CH3:22]

Participants

6

Reactant 3

HCID 3776IsopropanolHCID 77452-Methyl-1-pentanol2×HCID 16682931Triisobutylaluminum

Product 1

HCID 86741194HCID 86741194, compound

Reagents, catalysts & solvents 2

HCID 8078CyclohexaneSolventHCID 8900HeptaneSolvent

Procedure

To 10 ml of 1.085M DBM in heptane and 0.33 ml of 0.92M TIBAL (as above) is slowly added a mixture of 2-methyl-1-pentanol (0.9 ml, 7.25 mmoles) and isopropanol (1.1 ml, 14.45 mmoles), diluted to 5 ml with cyclohexane. A slurry is formed which dissolves on addition of 0.9 ml (7.25 mmoles) of 2-methyl-1-pentanol.

Workup

  1. customA slurry is formed which

Sources & evidence

ORD record
ord-ef08f53b4b014f8b9aa6be9b60786c08
Source dataset
uspto-grants-1987_01
Patent number
US04634786

Reaction notes

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