Methylmalonic Acid → Bromisobernsteinsaure

HRID 980119Notes

Reaction equation

[P].[Br:2]Br.[CH3:4][CH:5]([C:9]([OH:11])=[O:10])[C:6]([OH:8])=[O:7]>>[Br:2][C:5]([CH3:4])([C:9]([OH:11])=[O:10])[C:6]([OH:8])=[O:7]

Participants

Reactant 3

HCID 487Methylmalonic Acid

HCID 24408Bromine

HCID 5462309Phosphorus

Product 1

HCID 20164416Bromisobernsteinsaure

Procedure

Phosphorus and Bromine is added into dry 2-methylmalonic acid according to the procedure of Braun, in Berichte 42, p. 839 (1909) to form 2-Bromo-2-methyl malonic acid.

Sources & evidence

ORD record: ord-ea203321e35a4bb1af6086c40f7c7926
Source dataset: uspto-grants-1987_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04636396

Reaction notes

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