L-Lysine → L-Isoleucine

HRID 980497Notes

Reaction equation

HRID 980497 reaction equation
[NH2:1][C@H:2]([C:7]([OH:9])=[O:8])[CH2:3][CH:4]([CH3:6])C.N[C@H:11](C(O)=O)CCCCN.N[C@H](C(O)=O)CCSC.N[C@H](C(O)=O)[C@@H](C)O.N[C@H](C(O)=O)C(C)C.[Ca].[P]>[Fe]>[NH2:1][C@H:2]([C:7]([OH:9])=[O:8])[C@H:3]([CH2:4][CH3:6])[CH3:11]

Participants

9

Reactant 7

HCID 5962L-LysineHCID 6106L-LeucineHCID 6137L-MethionineHCID 6287L-ValineHCID 6288L-ThreonineHCID 5460341CalciumHCID 5462309Phosphorus

Product 1

HCID 6306L-Isoleucine

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

L-leucine (1.8 g); L-lysine 1.3 ); L-methionine (1.76 g); L-methylalanine (2.5 g); L-threonine (1.4 g); L-valine (1.5 g); suitable salts containing calcium (1 g); phosphorus (0.8 g) and iron (15 g).

Sources & evidence

ORD record
ord-192a65572efa4de7a49bde8db3d3c4d1
Source dataset
uspto-grants-1987_01
Patent number
US04638013

Reaction notes

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