Succinic anhydride → HCID 13361993, compound

HRID 980940Notes

Reaction equation

HRID 980940 reaction equation
[Cl:1][C:2]1[CH:16]=[CH:15][CH:14]=[C:13]([Cl:17])[C:3]=1[CH:4]=[N:5][CH2:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.[C:18]1(=[O:24])[O:23][C:21](=[O:22])[CH2:20][CH2:19]1>CC1C=CC=CC=1C>[CH2:6]([N:5]1[CH:4]([C:3]2[C:2]([Cl:1])=[CH:16][CH:15]=[CH:14][C:13]=2[Cl:17])[CH:20]([C:21]([OH:23])=[O:22])[CH2:19][C:18]1=[O:24])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

Participants

4

Reactant 2

HCID 7922Succinic anhydrideHCID 1336198494655-25-1

Product 1

HCID 13361993HCID 13361993, compound

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

2,6-Dichlorobenzylidene-benzylamine [100 gm. 0.39 mole] and succinic anhydride [39.0 gm. 0.39 mole] were refluxed with O-xylene [500 ml] for 12 hours. On cooling, the precipitate was filtered and washed with a little ethanol. The solid was recrystallized from ethanol to give white needles. After drying over boiling isobutyl methyl ketone and under vacuum for 5 hours, the title compound had a melting point of 179°-181° C.

Workup

  1. temperatureOn cooling
  2. filtrationthe precipitate was filtered
  3. washwashed with a little ethanol
  4. customThe solid was recrystallized from ethanol
  5. customto give white needles
  6. customAfter drying

Sources & evidence

ORD record
ord-22326efc39c4437692977a601472d250
Source dataset
uspto-grants-1987_01
Patent number
US04639529

Reaction notes

Loading…