HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Dioxide → 1,7-Octadien-3-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | 1,3-Butadiene | HCID 7845 | — |
| Reactant | 2,7-Octadien-1-ol | HCID 32012 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 1,7-Octadien-3-ol | HCID 545738 | 10.1% |
Reaction Steps
The thus deposited and separated palladium complex was placed again in the autoclave, to which 0.5 mol of 1,3-butadiene, 1 mol of water, 0.6 mol of carbon dioxide, and 63 ml of dimethyl formamide were fed afresh. Then, the reaction was conducted under the same conditions as mentioned above, with the consequence that 0.158 mol of 2,7-octadien-1-ol, and 0.016 mol of 1,7-octadien 3-ol were produced.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04990698 |
| Source dataset | uspto-grants-1991_02 |
| ORD ID | ord-92996d6a6ae842e98deb3a833302f9b2 |
| Source note | uspto-grants-1991_02 |