Carbon Dioxide → 1,7-Octadien-3-ol

HRID 981407Notes

Reaction equation

HRID 981407 reaction equation
C=CC=C.O.C(=O)=[O:7].[CH2:9](O)[CH:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH2:16]>CN(C)C=O>[CH2:9]=[CH:10][CH:11]([OH:7])[CH2:12][CH2:13][CH2:14][CH:15]=[CH2:16]

Participants

6

Reactant 4

HCID 280Carbon DioxideHCID 962WaterHCID 78451,3-ButadieneHCID 320122,7-Octadien-1-ol

Product 1

HCID 5457381,7-Octadien-3-olYield 10.1%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

The thus deposited and separated palladium complex was placed again in the autoclave, to which 0.5 mol of 1,3-butadiene, 1 mol of water, 0.6 mol of carbon dioxide, and 63 ml of dimethyl formamide were fed afresh. Then, the reaction was conducted under the same conditions as mentioned above, with the consequence that 0.158 mol of 2,7-octadien-1-ol, and 0.016 mol of 1,7-octadien 3-ol were produced.

Workup

  1. customseparated palladium complex

Sources & evidence

ORD record
ord-92996d6a6ae842e98deb3a833302f9b2
Source dataset
uspto-grants-1991_02
Patent number
US04990698

Reaction notes

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