Dimethylthiocarbamoyl chloride → HCID 20068248, compound

HRID 982544Notes

Reaction equation

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([N+:16]([O-:18])=[O:17])[CH:11]=2)=[O:9])=[CH:4][CH:3]=1.[CH3:19][N:20]([CH3:24])[C:21](Cl)=[S:22]>>[CH3:19][N:20]([CH3:24])[C:21](=[S:22])[O:1][C:2]1[CH:7]=[CH:6][C:5]([C:8](=[O:9])[C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([N+:16]([O-:18])=[O:17])[CH:11]=2)=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 27871Dimethylthiocarbamoyl chloride

HCID 19026878HCID 19026878, compound

Product 1

HCID 20068248HCID 20068248, compoundYield 84%

Procedure

Following the procedure described in Preparation I and starting from 18 g (0.07407 mol) of 4-hydroxyphenyl 3-nitrophenyl methanone and 12.3 g (0.0992 mol) of dimethylthiocarbamoyl chloride, 20.5 g (yield: 84%) of O-4-(3-nitrobenzoyl)phenyl dimethylthiocarbamate are obtained.

Workup

customdescribed in Preparation I

Sources & evidence

ORD record: ord-35f2e7591fdd4bfea4935fa45bf3a724
Source dataset: uspto-grants-1991_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04996347

Reaction notes

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