反应详情

A similar crossover experiment using the alpha-chloroalkenylalanates derived from 1-chloro-1-octyne/sodium triethylaluminum hydride and 1-chloro-1-dodecyne/sodium trimethylaluminum hydride produced (by GC examination of a hydrolyzed aliquot) only the intramolecular transfer products cis-3-decene (72%) and cis-2-tridecene (66%). Neither of the crossover adducts cis-3-tetradecene and cis-2-nonene was detected.