HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Chloro-1-octyne sodium triethylaluminum hydride → cis-3-Decene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Chloro-1-octyne sodium triethylaluminum hydride | HCID 86744635 | — |
| Reactant | 1-Chloro-1-dodecyne sodium trimethylaluminum hydride | HCID 86744636 | — |
| Product | 2-Tridecene, (2Z)- | HCID 5362714 | 66% |
| Product | cis-3-Decene | HCID 5362723 | 72% |
Reaction Steps
A similar crossover experiment using the alpha-chloroalkenylalanates derived from 1-chloro-1-octyne/sodium triethylaluminum hydride and 1-chloro-1-dodecyne/sodium trimethylaluminum hydride produced (by GC examination of a hydrolyzed aliquot) only the intramolecular transfer products cis-3-decene (72%) and cis-2-tridecene (66%). Neither of the crossover adducts cis-3-tetradecene and cis-2-nonene was detected.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04996340 |
| Source dataset | uspto-grants-1991_02 |
| ORD ID | ord-6085a23a737f4fc1bdce4f389c6da37c |
| Source note | uspto-grants-1991_02 |