HuagongsheHuagongshe Chemistry Print Report · For research reference only
13-Oxabicyclo[10.1.0]tridecane → Cyclododecanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 13-Oxabicyclo[10.1.0]tridecane | HCID 9248 | — |
| Catalyst | Lithium Chloride | HCID 433294 | — |
| Solvent | 1,3-Dimethyl-2-imidazolidinone | HCID 6661 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | Cyclododecanone | HCID 13246 | 94% |
Reaction Steps
For example, German Patent DE3744094 discloses a technique where an epoxycyclododecane is isomerized by using N-methylpyrrolidone or N,N′-dimethylethyleneurea as a solvent and using lithium chloride as a catalyst and thereby a cyclododecanone is obtained in a yield of 94%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06861563B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-1fb537af28774adc941b5f3d5d94fdeb |
| Source note | uspto-grants-2005_03 |