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HRID986339

反应详情

EQUATION

反应方程式

HRID 986339 的结构方程式

REACTANTS

反应物

1
结构：CC1(C)Nc2ccccc2NC1=O
HCID595203

3,3-dimethyl-3,4-dihydroquinoxalin-2(1H)-one

C10H12N2O

PRODUCTS

生成物

1
结构：CC1(C)N[C@@H]2CCCC[C@@H]2NC1=O
HCID12886757

(4aR,8aS)-3,3-Dimethyloctahydroquinoxalin-2(1H)-one

C10H18N2O

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Rh]
催化剂HCID23948

Rhodium

Rh

PROCEDURE

实验过程

In a manner analogous with the foregoing, 3,3-dimethyl-3,4-dihydroquinoxalin-2-one is hydrogenated at about 130° C. and 1500 psi in the presence of rhodium (5%) on charcoal in 2 hours, to yield cis-3,3-dimethyl-decahydroquinoxalin-2-one.

WORKUP

后处理

  1. customis hydrogenated at about 130° C.