HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → Bicyclo[2.2.1]hept-5-ene-2-methanol norbornene maleic anhydride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | Maleic Anhydride | HCID 7923 | — |
| Reactant | 2-Norbornene | HCID 10352 | — |
| Reactant | Bicyclo(2.2.1)hept-5-ene-2-methanol | HCID 78946 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | Bicyclo[2.2.1]hept-5-ene-2-methanol norbornene maleic anhydride | HCID 86759190 | 57% |
Reaction Steps
To 70 ml of tetrahydrofuran was added 0.05 M of norbornylene, 0.15 M of bicyclo[2.2.1]hept-5-ene-2-methanol, 0.2 M of maleic anhydride and 0.4 g of AIBN. The resulting solution was reacted at 67° C. for 8 hours. Thereafter, a polymer was precipitated and filtered in petroleum ether/ether (1/1) solution, to obtain the title polymer (yield: 57%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06630281B2 |
| Source dataset | uspto-grants-2003_10 |
| ORD ID | ord-491b8530aac04a57b8bb051cb19f6fe2 |
| Source note | uspto-grants-2003_10 |