Pyrrole → 5-[4-(6Acetyloxy-hexyloxy)-phenyl]-10,15,20-tris(3,5-didecyloxy-phenyl)-porphyrin
Reaction equation
[CH2:1]([O:11][C:12]1[CH:13]=[C:14]([CH:17]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:19]=1)[CH:15]=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH:31]([C:33]1[CH:49]=[CH:48][C:36]([O:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][O:44][C:45](=[O:47])[CH3:46])=[CH:35][CH:34]=1)=O.[NH:50]1[CH:54]=[CH:53][CH:52]=[CH:51]1>>[C:45]([O:44][CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][O:37][C:36]1[CH:48]=[CH:49][C:33]([C:31]2[C:54]3[NH:50][C:51]([C:15]([C:14]4[CH:17]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:19]=[C:12]([O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:13]=4)=[C:51]4[N:50]=[C:54]([C:15]([C:14]5[CH:17]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:19]=[C:12]([O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:13]=5)=[C:54]5[NH:50][C:51](=[C:15]([C:14]6[CH:13]=[C:12]([O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:19]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:17]=6)[C:51]6[CH:52]=[CH:53][C:54]=2[N:50]=6)[CH:52]=[CH:53]5)[CH:53]=[CH:52]4)=[CH:52][CH:53]=3)=[CH:34][CH:35]=1)(=[O:47])[CH3:46]Participants
4
Procedure
The title compound was prepared according to the method described in Example 15 above from 3,5-didecyloxy-benzaldehyde (see Example 13), acetic acid 6-(4-formyl-phenoxy)-hexyl ester (see Example 7) and pyrrole.
Sources & evidence
- ORD record
- ord-8ef96656d224496083987ac5da3a7cec
- Source dataset
- uspto-grants-2003_10
- Patent number
- US06630128B1
Reaction notes
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