Pyrrole → 5-[4-(12-Acetyloxy-dodecyloxy)-phenyl]-10,15,20-tris-(3,5-didecyloxy-phenyl)-porphyrin
Reaction equation
[CH2:1]([O:11][C:12]1[CH:13]=[C:14]([CH:17]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:19]=1)[CH:15]=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH:31]([C:33]1[CH:55]=[CH:54][C:36]([O:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][O:50][C:51](=[O:53])[CH3:52])=[CH:35][CH:34]=1)=O.[NH:56]1[CH:60]=[CH:59][CH:58]=[CH:57]1>>[C:51]([O:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][O:37][C:36]1[CH:54]=[CH:55][C:33]([C:31]2[C:60]3[NH:56][C:57]([C:15]([C:14]4[CH:17]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:19]=[C:12]([O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:13]=4)=[C:57]4[N:56]=[C:60]([C:15]([C:14]5[CH:17]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:19]=[C:12]([O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:13]=5)=[C:60]5[NH:56][C:57](=[C:15]([C:14]6[CH:13]=[C:12]([O:11][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH:19]=[C:18]([O:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH:17]=6)[C:57]6[CH:58]=[CH:59][C:60]=2[N:56]=6)[CH:58]=[CH:59]5)[CH:59]=[CH:58]4)=[CH:58][CH:59]=3)=[CH:34][CH:35]=1)(=[O:53])[CH3:52]Participants
4
Procedure
The title compound was prepared according to the method described in Example 24 above from 3,5-didecyloxy-benzaldehyde (see Example 13), acetic acid 12-(4-formyl-phenoxy)-dodecyl ester (see Example 6) and pyrrole.
Sources & evidence
- ORD record
- ord-02d97293f9b44c0499db6e7c645cc259
- Source dataset
- uspto-grants-2003_10
- Patent number
- US06630128B1
Reaction notes
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