Guaiacol → HCID 18008626, compound

HRID 987369Notes

Reaction equation

HRID 987369 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[OH:9].[CH3:10][CH2:11][CH2:12][CH2:13][CH:14]([CH:16]([CH3:18])C)C.[CH3:19][CH2:20]CC(CC(C)C)C.CC(CC(C(C)C)C)C>>[CH3:1][O:2][C:3]1[CH:8]=[C:7]([CH2:19][CH2:20][CH2:18][CH2:16][CH2:14][CH2:13][CH2:12][CH2:11][CH3:10])[CH:6]=[CH:5][C:4]=1[OH:9]

Participants

3

Reactant 2

HCID 460GuaiacolHCID 2637413987-01-4

Product 1

HCID 18008626HCID 18008626, compound

Conditions

Temperature
120 °C

Procedure

2-Methoxyphenol (5 mol, 621 g), dry Amberlyst 15 (50 g) and tripropylene (5.5 mol, 694 g, 951 ml) were placed in a 3000 ml 3N RBF. The mixture was heated and maintained at 120° C. under vigorous stirring for 7 hrs. After cooling to ambient temperature, the reaction mixture was filtered and distilled to obtain 2-methoxy-4-nonylphenol in vacuo.

Workup

  1. temperatureThe mixture was heated
  2. temperatureAfter cooling to ambient temperature
  3. filtrationthe reaction mixture was filtered
  4. distillationdistilled

Sources & evidence

ORD record
ord-8926835667504e3ca3f10a57c80d3118
Source dataset
uspto-grants-2003_10
Patent number
US06632410B2

Reaction notes

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