1-Butene → HCID 23503844, compound

On the other hand, in an egg-plant type flask with an inner volume of 25 ml replaced with argon, 5 ml of purified toluene and 1.2 mg of dichloro{2,2′-thiobis[4-methyl-6-(tert-butyl)phenolato} titanium were mixed by stirring, and then charged into the autoclave. The molar ratio of [Al]/[Ti] of the catalyst solution prepared then was 8,000. After the catalyst solution was mixed by stirring at room temperature for 10 minutes, 31.5 ml of 1-hexene and 14 g of 1-butene were charged and the polymerization was carried out at 40° C. for 1 hour. Then, the polymerization was terminated by adding methanol. Further, the mixture was charged into about 10-fold acidic methanol, and the precipitated polymer was filtered to be dried at 80° C. for about 2 hours. As a result, 1.1 g of poly(1-butene/1-hexene) copolymer was obtained. Mw of the polymer obtained was 582×104, Mn was 227×104, Mw/Mn was 2.6, and no crystal fusion peak by DSC was detected. The glass transition temperature (Tg) was observed at −36° C. and the polymer was amorphous.

1. additionwere mixed
2. additioncharged into the autoclave
3. customThe molar ratio of [Al]/[Ti] of the catalyst solution prepared
4. additionAfter the catalyst solution was mixed
5. stirringby stirring at room temperature for 10 minutes
6. customThen, the polymerization was terminated
7. additionby adding methanol
8. additionFurther, the mixture was charged into about 10-fold acidic methanol
9. filtrationthe precipitated polymer was filtered
10. customto be dried at 80° C. for about 2 hours

ORD record

ord-106a28948e4f4c039f25dfa9a07942d5

Source dataset

uspto-grants-2003_10

DOI

10.6084/m9.figshare.5104873.v1

Patent number

US06632900B2