1H-1,2,4-Triazole → HCID 131723224, compound

HRID 991162Notes

Reaction equation

HRID 991162 reaction equation
[NH:1]1[CH:5]=[N:4][CH:3]=[N:2]1.[F:6][C:7]1[C:12]([B:13]([C:25]2[C:30]([F:31])=[C:29]([F:32])[C:28]([F:33])=[C:27]([F:34])[C:26]=2[F:35])[C:14]2[C:19]([F:20])=[C:18]([F:21])[C:17]([F:22])=[C:16]([F:23])[C:15]=2[F:24])=[C:11]([F:36])[C:10]([F:37])=[C:9]([F:38])[C:8]=1[F:39].[CH2:40]([N:58]([CH2:60][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH2:72][CH2:73][CH2:74][CH2:75][CH2:76][CH3:77])[CH3:59])[CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57]>C1(C)C=CC=CC=1>[F:31][C:30]1[C:25]([B:13]([C:12]2[C:7]([F:6])=[C:8]([F:39])[C:9]([F:38])=[C:10]([F:37])[C:11]=2[F:36])[C:14]2[C:15]([F:24])=[C:16]([F:23])[C:17]([F:22])=[C:18]([F:21])[C:19]=2[F:20])=[C:26]([F:35])[C:27]([F:34])=[C:28]([F:33])[C:29]=1[F:32].[F:31][C:30]1[C:25]([B:13]([C:12]2[C:7]([F:6])=[C:8]([F:39])[C:9]([F:38])=[C:10]([F:37])[C:11]=2[F:36])[C:14]2[C:15]([F:24])=[C:16]([F:23])[C:17]([F:22])=[C:18]([F:21])[C:19]=2[F:20])=[C:26]([F:35])[C:27]([F:34])=[C:28]([F:33])[C:29]=1[F:32].[CH2:60]([NH+:58]([CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH3:57])[CH3:59])[CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH2:72][CH2:73][CH2:74][CH2:75][CH2:76][CH3:77].[NH:1]1[CH:5]=[N:4][C-:3]=[N:2]1

Participants

5

Reactant 3

HCID 92571H-1,2,4-TriazoleHCID 77709DistearylmethylamineHCID 582056Tris(pentafluorophenyl)borane

Product 1

HCID 131723224HCID 131723224, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

1,2,4-triazole (0.1349 g, 1.953 mmol), tris(pentafluorophenyl)borane (2.0000 g, 3.9063 mmol) and dioctadecylmethylamine (1.0469 g, 1.9531 mmol) were placed in a 50 mL flask, taken up in 21 mL of toluene and refluxed under argon for 5 hours. The volatiles were then stripped under vacuum. Yield, 2.702 g, 84.92 percent.

Workup

  1. temperaturerefluxed under argon for 5 hours
  2. customYield

Sources & evidence

ORD record
ord-8bc796428a6447a88c999537e1806b39
Source dataset
uspto-grants-2002_10
Patent number
US06462156B2

Reaction notes

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