HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosgene → 1-Isocyanato-3-nitroadamantane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosgene | HCID 6371 | — |
| Reactant | 1-Amino-3-nitroadamantane | HCID 18410483 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 1-Isocyanato-3-nitroadamantane | HCID 13237684 | 90% |
Reaction Steps
10 mmole of 1-amino-3-nitroadamantane obtained by the method of Example 66 was dissolved in toluene (100 ml). To the resultant solution, 12 mmole of phosgene was added at the room temperature and stirred for 6 hours. As a result, The conversion of 1-amino-3-nitroadamantane was 99%, and 1-isocyanato-3-nitroadamantane (yield 90%) was formed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06468487B1 |
| Source dataset | uspto-grants-2002_10 |
| ORD ID | ord-7dcf062a33334c4996fd91fea700d3d8 |
| Source note | uspto-grants-2002_10 |