HCID 178443619, compound → Phenetole

HRID 992779Notes

Reaction equation

HRID 992779 reaction equation
[O-:1][CH2:2][CH3:3].CN(P(=N[P+](N=P(N(C)C)(N(C)C)N(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=[PH2]N(CC[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])CCCCCCCC)(N(C)C)N(C)C)C>P(N(C)C)(N(C)C)N(C)C>[CH2:2]([O:1][C:29]1[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1)[CH3:3]

Participants

3

Reactant 1

HCID 178443619HCID 178443619, compound

Product 1

HCID 7674PhenetoleYield 86%

Reagents, catalysts & solvents 1

HCID 15355Hexamethylphosphorous triamideSolvent

Procedure

The reaction was carried out completely in the same manner as in Example 1, except that tris[tris(dimethylamino)phosphoranylideneamino](dioctylamino)phosphoranylideneamino phosphonium ethoxide: [(Me2N)3P═N]3P+{N═P[N(C8H17)2]}, C2H5O− was used instead of tetrakis[tris(dimethylamino)phosphoranylideneamino]phosphonium methoxide in Example 1. Objective ethoxybenzene was produced in the yield of 86%.

Sources & evidence

ORD record
ord-673f3a6c71334a6790f2aa54d40eeb68
Source dataset
uspto-grants-2002_10
Patent number
US06469224B1

Reaction notes

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