2-甲苯缩水甘油醚

o-CRESYL GLYCIDYL ETHER

HCID 16640CAS 2210-79-9

基本信息

标准SMILES
Cc1ccccc1OCC1CO1
InChIKey
KFUSXMDYOPXKKT-UHFFFAOYSA-N
分子式
C10H12O2
平均分子量
164.2 g/mol
单同位素质量
164.08372962

概述

O-cresyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)

名称与标识

首选名称
o-CRESYL GLYCIDYL ETHER
IUPAC
2-[(2-methylphenoxy)methyl]oxirane
中文名
2-甲苯缩水甘油醚
英文名
2-[(2-Methylphenoxy)methyl]oxirane
分子式
C10H12O2
分子量
164.2

名称与别名

2210-79-9O-CRESYL GLYCIDYL ETHERGlycidyl 2-methylphenyl etherGlycidyl o-tolyl ether2-Methylphenyl glycidyl etherAraldite DY 0231,2-Epoxy-3-(2-methylphenoxy)propane1-(2-Methylphenoxy)-2,3-epoxypropaneDTXSID80248621-(o-Methylphenoxy)-2,3-epoxypropane((2-Methylphenoxy)methyl)oxirane1,2-Epoxy-3-(o-tolyloxy)propane
展开更多名称
邻基缩水甘油醚邻甲苯缩水甘油醚邻甲酚缩水甘油醚2-甲苯缩水甘油醚邻甲苯基缩水甘油酷邻甲苯基缩水甘油醚鄰甲酚基縮水甘油基醚顺-2-壬烯-1-醇3-环氧丙基邻甲苯基醚环氧丙基2-甲基苯基醚DY 023Nsc11571o-cresylHeloxy 62Epodil 742aralditedy0232-((o-Tolyloxy)o-Cresolglycidylethero-Kresol-glycidaether
Glycidyl o-methylphenyl etherPropane, 1,2-epoxy-3-(o-tolyloxy)-Oxirane, ((2-methylphenoxy)methyl)-(2-Methylphenoxymethyl)oxirane2,3-Epoxypropyl o-tolyl etherNSC-11571NSC-20291Oxirane, [(2-methylphenoxy)methyl]-

数据库标识

CAS
2210-79-9
PubChem CID
16640
DTXSID
DTXSID8024862
ChEMBL
CHEMBL1445408
UNII
8Z744RD471
EC Number
218-645-3
Nikkaji
J475.256B、J59.926C

性质

结构计算性质

XLogP
2.4
极性表面积
21.8 Ų
氢键供体
0
氢键受体
2
可旋转键
3
重原子
12

实验与物化性质

PolymersPlastics & Rubber -> Glycidyl Ethers
Density · 2 条

1.09 at 68 °F (NTP, 1992) - Denser than water; will sink

Relative density (water = 1): 1.08

Solubility · 2 条

less than 1 mg/mL at 72 °F (NTP, 1992)

Solubility in water: none

Flash Point · 3 条

200 °F (NTP, 1992)

200 °F

113 °C c.c.

Boiling Point · 2 条

498 °F at 760 mmHg (NTP, 1992)

at 0.533kPa: 109-111 °C

Vapor DensityRelative vapor density (air = 1): 5.7

物理化学性质

沸点
109 · 109-111 °C/4 mmHg (lit.)
密度
1.079 g/mL · 1.079 g/mL at 25 °C (lit.)
蒸气密度
1 · >1 (vs air)
蒸气压
0.514 Pa · 0.514Pa at 20℃
折射率
20 · n20/D 1.529(lit.)
闪点
230 °F · >230 °F

安全与法规

GHS分类

GHS Classification · 6 条

Warning

H315: Causes skin irritation [Warning Skin corrosion/irritation]

P203, P261, P264, P272, P273, P280, P302+P352, P318, P321, P332+P317, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P203, P261, P264, P272, P273, P280, P302+P352, P318, P321, P332+P317, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)

危害信息

Regulatory Information · 5 条

Chemical: Oxirane, [(2-methylphenoxy)methyl]-

Oxirane, 2-[(2-methylphenoxy)methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[(2-methylphenoxy)methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

Status: Active Update: 05-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14553

Oxirane, [(2-methylphenoxy)methyl]-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Oxirane, [(2-methylphenoxy)methyl]-: Environment tier I assessment
DOT LabelClass 9
Fire Hazards · 2 条

This chemical is combustible. (NTP, 1992)

Combustible.

Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin and eyes, and allergic dermatitis.
Hazards SummaryMay cause skin sensitization; [ICSC] Danger of skin sensitization; [MAK]

安全与防护

Fire Fighting · 2 条

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Use water spray, foam, powder, carbon dioxide.

First Aid Measures · 4 条

Fresh air, rest.

Remove contaminated clothes. Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth.

First Aid · 1 条

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Safe StorageSeparated from strong oxidants, strong bases, strong acids and amines. Cool. Keep in the dark.
Nonfire Spill Response · 1 条

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Spillage Disposal · 1 条

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

毒理信息

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Signs and Symptoms · 3 条

Cough. Sore throat.

Redness. Pain.

Redness.

Toxicity DataLC50 (rat) = 6,090 mg/m3/4h

安全数据

wgk
2
tsca
TSCA listed
RTECS号
TZ3700000
包装类别
III
危险等级
9
存储类别
10 - Combustible liquids

化学与工业

用途与制造

Uses · 2 条

Glycidyl ethers are used as reactive diluents in epoxy resins. [LaDou, p. 550]

Plastic Composites Manufacturing [Category: Industry]

U.S. Production2023: 250,000 - <400,000 lb
Consumer UsesViscosity modifiers
Industry UsesDiluent
Household ProductsInformation on 3 consumer products that contain O-Cresyl glycidyl ether in the following categories is provided:
General Manufacturing Information · 2 条

Custom Compounding of Purchased Resins

Oxirane, 2-[(2-methylphenoxy)methyl]-: ACTIVE

应用领域

应用2-甲苯缩水甘油醚是高粘度环氧树脂的有效稀释剂,由于其特有的结构和位阻性,它在很多性能上已接近或超过双环氧类稀释剂,特别在耐溶剂性和耐水性能上明显优于其它稀释剂。

试剂价格

L10136 · 100g
环氧丙基 2-甲基苯基 醚, tech. 85%Glycidyl 2-methylphenyl ether, tech. 85% — 668元
L10136 · 25g
环氧丙基 2-甲基苯基 醚, tech. 85%Glycidyl 2-methylphenyl ether, tech. 85% — 215元

供应商50 家

常州市弘裕化工有限公司0519-89996110 13813691203 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
上海麦克林生化科技股份有限公司021-50706066 15221275939 · [email protected]
湖北鑫杰成化工科技有限公司13554075426 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

相关反应

20 条

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