二茂铁 → 二茂铁

HRID 249569

反应方程式

HRID 249569 反应方程式
Cl[Sn]Cl.[Cl:4][CH2:5][CH2:6][CH2:7][C:8]([C-:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1)=[O:9].[CH-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1.[Fe+2:20].[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[CH-:26]1[CH:30]=[CH:29][CH:28]=[CH:27]1.[Fe+2].[Cl:32][CH2:33][CH2:34][CH2:35][C:36]([C-]1C=CC=C1)=[O:37].[C-]1(C(=O)CCC[Cl:52])C=CC=C1.[Fe+2]>C(Cl)Cl.[Al+3].[Cl-].[Cl-].[Cl-].O=[Pt]=O.C(O)(=O)C>[Cl:4][CH2:5][CH2:6][CH2:7][C:8]([C-:10]1[CH:14]=[CH:13][CH:12]=[CH:11]1)=[O:9].[CH-:15]1[CH:19]=[CH:18][CH:17]=[CH:16]1.[Fe+2:20].[CH-:21]1[CH:25]=[CH:24][CH:23]=[CH:22]1.[CH-:26]1[CH:30]=[CH:29][CH:28]=[CH:27]1.[Fe+2:20].[Cl:32][CH2:33][CH2:34][CH2:35][C:36]([Cl:52])=[O:37]

参与物

11

反应物 4

HCID 7611二茂铁HCID 24479氯化亚锡HCID 178520619HCID 178520619，化合物HCID 178520620HCID 178520620，化合物

产物 3

HCID 7611二茂铁HCID 783704-氯丁酰氯HCID 178520619HCID 178520619，化合物

试剂、催化剂与溶剂 4

HCID 345198二氧化铂催化剂HCID 6451240三氯化铝催化剂HCID 176醋酸溶剂HCID 6344二氯甲烷溶剂

实验过程

In an inert atmosphere, 170 mg of PtO2.xH2O (containing 80% of Pt) and 5 mg of anhydrous SnCl2 are introduced into the glass beaker. 120 cm3 of glacial acetic acid and 29.1 g (0.10 mol) of 4-chlorobutyroylferrocene whose main impurities are 1.4% by weight of ferrocene and 0.88% by weight of 1,1'-di(4-chlorobutyroyl)ferrocene are then poured in. This 4-chlorobutyroylferrocene was obtained in the customary manner by a reaction of the Friedel-Crafts type between ferrocene and 4-chlorobutyryl chloride in CH2Cl2 in the presence of AlCl3 as catalyst, followed by recrystallisation of the crude product obtained from hexane.

后处理

  1. additionare introduced into the glass beaker
  2. additionare then poured in

来源与证据

ORD记录
ord-7535c6cada5e4d8aa4c298bdb54a4fc2
来源数据集
uspto-grants-1993_05
专利号
US05214175

关联笔记

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