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结构：CC(=O)O[BH-](OC(C)=O)OC(C)=O.[Na+]
HCID5049666

Sodium triacetoxyborohydride

sodium triacetyloxyboranuide

C6H10BNaO6211.94 g/molCAS 56553-60-7
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IDENTITY

结构与身份

标准 SMILES
CC(=O)O[BH-](OC(C)=O)OC(C)=O.[Na+]
InChIKey
HHYFEYBWNZJVFQ-UHFFFAOYSA-N
分子式
C6H10BNaO6
平均分子量
211.94 g/mol
单同位素质量
212.0468125

COMPUTED

结构计算性质

已同步
极性表面积
78.9 Ų
氢键供体
0
氢键受体
7
可旋转键
6
重原子
14
形式电荷
0
复杂度
192

PROPERTIES

实验与物化性质

来源：PubChem
Physical Description

White crystalline powder; [Alfa Aesar MSDS]

GHS

GHS 分类

来源：PubChem
GHS Classification

Danger

H228 (38.3%): Flammable solid [Danger Flammable solids]；H260 (68.9%): In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases]；H261 (31.1%): In contact with water releases flammable gas [Danger Substances and mixtures which in contact with water, emit flammable gases]；H314 (11.1%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H315 (83%): Causes skin irritation [Warning Skin corrosion/irritation]；H318 (65.1%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H335 (26%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H360 (50.2%): May damage fertility or the unborn child [Danger Reproductive toxicity]

P203, P210, P223, P231+P232, P240, P241, P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P335+P334, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P318, P319, P321, P332+P317, P362+P364, P363, P370+P378, P402+P404, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 235 reports by companies from 20 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

HAZARDS

危害信息

来源：PubChem
Regulatory Information

Status: Active Update: 22-02-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/20512；Status: Active Update: 11-11-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/17743

Borate(1-), tris(acetato-.kappa.O)hydro-, sodium, (T-4)-: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary

Reacts with water evolving flammable gases; An irritant that may cause serious eye injury; [Alfa Aesar MSDS] See Lithium borohydride and Sodium borohydride. See Boric acid.

Hazard Classes and Categories

Flam. Sol. 2 (38.3%)；Water-react. 1 (68.9%)；Water-react. 3 (31.1%)；Skin Corr. 1B (11.1%)；Skin Irrit. 2 (83%)；Eye Dam. 1 (65.1%)；STOT SE 3 (26%)；Repr. 1B (50.2%)

REGULATORY

法规信息

来源：PubChem
Regulatory Information

Status: Active Update: 22-02-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/20512；Status: Active Update: 11-11-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/17743

Borate(1-), tris(acetato-.kappa.O)hydro-, sodium, (T-4)-: Does not have an individual approval but may be used under an appropriate group standard

USES

用途与制造

来源：PubChem
Uses

Used as a selective reducing agent in organic synthesis; [Merck Index]

ALIASES

名称与别名

共 60 条
4VU0JE4YSKDTXSID8074368Borate(1-), tris(acetato-kappaO)hydro-, sodium (1:1), (T-4)-RefChem:887964DTXCID5042089611-401-056553-60-7Borate(1-), tris(acetato-kappaO)hydro-, sodium, (T-4)-Sodium triacetoxyborohydrideSodium Triacetoxyborohydride (Technical Grade)C6H10BNaO6sodium trisacetoxyborohydridesodium triacetoxy-borohydrideNa(OAc)3BHNaB(OAc)3HNaBH(AcO)3NaBH(OAc)3sodium tnacetoxyborohydndesodium;triacetoxyboranuideUNII-4VU0JE4YSK

REACTIONS

参与反应

14 条
全部作为反应物作为生成物作为试剂作为催化剂作为溶剂