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Trisodium phosphate dodecahydrate

HCID 61473
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Grundinformationen

CAS
10101-89-0
Standard-SMILES
O.O.O.O.O.O.O.O.O.O.O.O.O=P([O-])([O-])[O-].[Na+].[Na+].[Na+]
InChIKey
ASTWEMOBIXQPPV-UHFFFAOYSA-K
Summenformel
H24Na3O16P
Durchschnittliche Molmasse
380,12 g/mol
Monoisotopische Masse
380,04950452

Namen und Bezeichner

Bevorzugter Name
Trisodium phosphate dodecahydrate
IUPAC
trisodium;phosphate;dodecahydrate
Englischer Name
Sodium phosphate tribasic dodecahydrate
Summenformel
H6NaO5P
Molmasse
140.01

Namen und Synonyme

Trisodium phosphate dodecahydrate10101-89-0Sodium phosphate tribasic dodecahydrateSodium phosphate dodecahydratePhosphoric acid, trisodium salt, dodecahydratesodium phosphate, tribasic, dodecahydratePhosphoric acid, trisodium salt, dodeahydrateB70850QPHRFRESH AQUAVEGE AQUADTXSID0049810RefChem:56038
Weitere Namen anzeigen
TSPSODIUM PHOSPHATE TRIBASICTRI-SODIUM PHOSPHATE DODECAHYDRATEsodiuM phosphatTRI-SODIUM ORTHOPHOSPHATE DODECAHYDRATEKH2PO9TSP, 12-HYDRATETSP dodecahydrateTRISODIUM PHOSHATE
DTXCID0029769600-151-8trisodium;phosphate;dodecahydrateMFCD00149198H24Na3O16PPhosphoric acid, sodium salt, hydrate (1:3:12)Trisodium phosphate (tert) dodecahydrateNa3PO4.12H2O

Datenbank-Bezeichner

CAS
10101-89-0
PubChem CID
61473
DTXSID
DTXSID0049810
UNII
B70850QPHR
EC Number
600-151-8

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
98,3 Ų
H-Brücken-Donoren
12
H-Brücken-Akzeptoren
16
Frei drehbare Bindungen
0
Schwere Atome
20
Formalladung
0
Komplexität
36,8

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Salts, Basic
Melting PointMelting point equals 164 to 170 ° F
Physical Description · 2 Einträge

Liquid; Dry Powder

Colorless to white crystals; [CAMEO]

Physikochemische Eigenschaften

Schmelzpunkt
75 °C · 75 °C
Dichte
1.62 g/mL · 1.62 g/mL at 25 °C
storage temp.
5 °C · Store at +5°C to +30°C.
Löslichkeit
2 O: · H2O: 0.5 M at 20 °C, clear, colorless
Aggregatzustand
Solid
Wichte
1.62 · 1.62
Farbe
White
PH
12 · 12 (10g/l, H2O, 20℃)
Wasserlöslichkeit
258 g/L · 258 g/L (20 ºC)
Merck
14 · 14,8662

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 1.3% (6 of 472) of reports.

Danger

H314 (20.8%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 472 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Phosphoric acid, trisodium salt, dodecahydrate

Phosphoric acid, trisodium salt, dodecahydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphoric acid, trisodium salt, dodecahydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Trisodium phosphate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Trisodium phosphate: Human health tier II assessment
Hazards SummaryCan cause burns to the eyes and skin; Harmful if ingested; [CAMEO] Aqueous solutions are highly alkaline; [HSDB] Dusts and solutions > 0.1% are corrosive to the eyes and possibly to the skin; [CHEMINFO]
Hazard Classes and Categories · 2 Einträge

Skin Corr. 1C (20.8%)

Skin corrosion - category 1B

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used to develop photos, clarify sugar, remove boiler scale, soften water, manufacture paper, tan leather, and make detergents; [HSDB] Used in food to increase alkalinity; [CHEMINFO]

Pulp and Paper Processing [Category: Industry]

U.S. Production2023: 1,112,954 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesCleaning agent
General Manufacturing InformationSoap, Cleaning Compound, and Toilet Preparation Manufacturing
Anwendungen · 2 Einträge

BeschreibungSodium phosphate tribasic dodecahydrate is also known as trisodium phospate or TSP. It is a highly soluble in water and widely used as a cleaning agent. The pH of a 1% solution is typically around 12, making this reagent sufficiently alkaline for saponification of grease and oils. In combination with surfactants, TSP is an excellent agent for cleaning everything from laundry to concrete driveways. This versatility and low manufacturing price made TSP the basis for a plethora of cleaning products sold in the mid-20th century. Trisodium phosphate is used in the isolation of mycobacteria, including culturing of tubercle bacilli. Has been used as a protein precipitant in certain applications and in co-precipitation and fractionization of nucleotides. May be used for the preservation of biologically active soil samples. Because of the alkaline pH, TSP disrupts cytoplasmic and outer membranes of Salmonella enterica cells making it useful in preventing the spread of bacteria. It is used in photographic developing, clarifying sugar, removing boiler scale, softening water and manufacturing of paper. They are added to many foods as an emulsifier to prevent oil separation. It can be utilized as a leavening agent. Some instances of these foods include the batter coating on breaded fish or chicken, and commercially baked cakes. Adding this item to food increases the shelf life of the food, maintaining the texture and visual aspect of the food.

Zugehörige Reaktionen

7
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Reaktionsgleichung von HRID 413620
HRID 413620als Eduktuspto-grants-2003_05
Reaktionsgleichung von HRID 435512
HRID 435512als Eduktuspto-grants-1983_08
Reaktionsgleichung von HRID 1282019
HRID 1282019als Eduktuspto-grants-2002_09
Reaktionsgleichung von HRID 1510813
HRID 1510813als Eduktuspto-grants-2012_07
Reaktionsgleichung von HRID 1510815
HRID 1510815als Eduktuspto-grants-2012_07
Reaktionsgleichung von HRID 1633392
HRID 1633392als Eduktuspto-grants-1984_10
Reaktionsgleichung von HRID 1957083
HRID 1957083als Eduktuspto-grants-1998_07

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Stabilität
Stable. Incompatible with strong acids. Keep dry.
InChI
1S/3Na.H3O4P.12H2O/c;;;1-5(2,3)4;;;;;;;;;;;;/h;;;(H3,1,2,3,4);12*1H2/q3*+1;;;;;;;;;;;;;/p-3
InChIKey
ASTWEMOBIXQPPV-UHFFFAOYSA-K
SMILES
O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O
LogP
-2.148 · -2.148 (est)
CAS Datenbank
10101 · 10101-89-0(CAS DataBase Reference)
EPA chemische Informationen
Trisodium phosphate dodecahydrate (10101-89-0)
Absorption
0.023 at · ≤0.023 at 280 in H2O at 0.5M≤0.035 at 260 in H2O at 0.5M

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

wgk
1
tsca
Yes
ridadr
UN 3262 8/PG 3
hs_code
28352300
RTECS-Nr.
TC9575000
risk_code
34-35-36/38
Toxizität
LD50 orally in Rabbit: 7400 mg/kg
hazard_code
C
safety_code
26-36/37/39-45-24/25
hazard_class
8
packing_group
III
Speicherklasse
8A - Combustible corrosive hazardous materials
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3

VerwendenSodium phosphate tribasic dodecahydrate is often used in the formulation of various buffers.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Caustic Soda(liquid)30%-48%Phosphate rock powderFood grade phosphoric acidOrthophosphorsureROCK PHOSPHATEFerric chloridephosphoric acid by wet processNatriumhydroxidSchwefelsureNatriumcarbonat

Nachgelagerte Produkte

Metal cleaner5-Butylpyridine-2-carbonitrileLignosulfonic acid, calcium salt5-Butylpyridin-3-carbonsaeureFilth removerSodium lignosulfonate