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Bisphenol A → Sebacic Acid

HRID 1058538
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Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 1058538
C1[C:10]2[C:5](=C[C:7]([C:11]([O:13]C)=[O:12])=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:15]([O:17]C)=[O:16].C(OC)(=O)CCCCCCCCC(OC)=O.[OH:35][C:36]1[CH:41]=[CH:40][C:39]([C:42]([C:45]2[CH:50]=[CH:49][C:48]([OH:51])=[CH:47][CH:46]=2)([CH3:44])[CH3:43])=[CH:38][CH:37]=1.O=[Sb]O[Sb]=O.P(OC)(OC)(OC)=O>C(O)CO.O.O.O.O.C([O-])(=O)C.[Mn+2].C([O-])(=O)C.CO>[C:15]([OH:17])(=[O:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:10][CH2:9][CH2:8][CH2:7][C:11]([OH:13])=[O:12].[OH:35][C:36]1[CH:37]=[CH:38][C:39]([C:42]([C:45]2[CH:46]=[CH:47][C:48]([OH:51])=[CH:49][CH:50]=2)([CH3:44])[CH3:43])=[CH:40][CH:41]=1
KomponentenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

10

Edukt 5

HCID 6623Bisphenol AHCID 7829Dimethyl sebacate2×HCID 10541Trimethyl PhosphateHCID 27652Oxo(oxostibanyloxy)stibaneHCID 61225Dimethyl-2,6-naphthalenedicarboxylate2×

Produkt 2

HCID 5192Sebacic Acid
HCID 6623
Bisphenol A

Reagenzien, Katalysatoren, Lösungsmittel 3

HCID 93021Manganese acetate tetrahydrateKatalysatorHCID 174Ethylene GlycolLösungsmittelHCID 887MethanolLösungsmittel

Versuchsvorschrift

Dimethyl 2,6-naphthalenedicarboxylate and dimethyl sebacate were dispersed in ethylene glycol and an addition product of two ethylene oxides tobisphenol A (BPA•2EO). Then, 0.029 part of manganese acetate tetrahydrate, 0.028 parts of antimony trioxide and 0.1% of spherical silica particles having a mean particle size of 0.3 μm were added to 100 parts of the total of dimethyl 2,6-naphthalenedicarboxylate and dimethyl sebacate, and heated with stirring to conduct the reaction. The temperature was elevated to 235° C. while removing methanol produced as a by-product. After the by-production of methanol was completed, 0.03 part of trimethyl phosphate was added thereto. Then, the pressure was reduced to 0.3 Torr while elevating the temperature to 285° C. to conduct the polymerization by changing the reaction time. Dyes described in JP-A-7-168309, compounds I-6 and I-24, were each further added to the solid matter in an amount of 54 ppm. The copolymerization composition ratios of sebacic acid (SA) and BPA•2EO and the intrinsic viscosities of polyesters thus obtained are shown in Table II-1.

Aufarbeitung

  1. temperatureheated
  2. customthe reaction
  3. customwas elevated to 235° C.
  4. customwhile removing methanol
  5. customproduced as a by-product
  6. customto 285° C.
  7. customthe polymerization
  8. additioneach further added to the solid matter in an amount of 54 ppm

Quellen und Nachweise

ORD-Eintrag
ord-832781fb6f304d9ab43d6a66d2f9a938
Quelldatensatz
uspto-grants-2003_02
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US06518004B2

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