Sodium Acetate → HCID 2885488, Verbindung

HRID 1069129Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1069129
[C:1]1([CH2:11][O:12][C:13]2[CH:20]=[CH:19][C:16]([CH:17]=O)=[CH:15][CH:14]=2)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.C([O-])(=O)C.[Na+].[S:26]1[CH2:32][C:30](=[O:31])[NH:29][C:27]1=[S:28]>C(O)(=O)C>[C:1]1([CH2:11][O:12][C:13]2[CH:20]=[CH:19][C:16]([CH:17]=[C:32]3[S:26][C:27](=[S:28])[NH:29][C:30]3=[O:31])=[CH:15][CH:14]=2)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1

Komponenten

5

Edukt 3

HCID 517045Sodium AcetateHCID 881941HCID 881941, VerbindungHCID 1201546Rhodanine

Produkt 1

HCID 2885488HCID 2885488, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

Under a nitrogen atmosphere in a round bottom flask 4-[(naphth-1-yl)methoxy]benzaldehyde (5.25 g, 20 mmol) was dissolved in 100 ml of acetic acid. To this solution was added sodium acetate (5.74 g, 70 mmol) and rhodanine (2.66 g, 20 mmol). The reaction mixture was raised to the reflux temperature and maintained at this temperature. The progress of the reaction was monitored by thin layer chomratography.

Aufarbeitung

  1. temperatureThe reaction mixture was raised to the reflux temperature
  2. temperaturemaintained at this temperature

Quellen und Nachweise

ORD-Eintrag
ord-b5bb25d61a364fe3bb4fa90dcbf4ea58
Quelldatensatz
uspto-grants-2001_06
Patentnummer
US06251928B1

Notizen zur Reaktion

Wird geladen…