Vinyl Acetate → 1,1-Ethanediol, 1,1-diacetate

HRID 1111242

Reaktionsgleichung

Reaktionsgleichung von HRID 1111242
[C:1]([O:4][CH:5]=[CH2:6])(=[O:3])[CH3:2]>[Pd](Cl)Cl.C(O)(=O)C>[C:1]([O:4][CH:5]([O:4][C:1](=[O:3])[CH3:2])[CH3:6])(=[O:3])[CH3:2]

Komponenten

4

Edukt 1

HCID 7904Vinyl Acetate

Produkt 1

HCID 2225361,1-Ethanediol, 1,1-diacetateAusbeute 2.504,6 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 24290Palladium ChlorideKatalysatorHCID 176Acetic AcidLösungsmittel

Versuchsvorschrift

The procedure of Example 9 was repeated except that 0.451 g of palladium chloride was used in place of palladium supported on activated carbon and the reaction was effected for 3 hours. GC analysis showed that 1.51 g of vinyl acetate and 32.1 g of ethylidene diacetate were formed with considerable amount of acetic acid.

Quellen und Nachweise

ORD-Eintrag
ord-a9b5c18e35584c908a6278b712e5c952
Quelldatensatz
uspto-grants-1990_12
Patentnummer
US04978778

Verknüpfte Notizen

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